css_path:

https://raw.githubusercontent.com/mangohero1985/slack_css/master/custom.css

config_path:

/Applications/Slack.app/Contents/resources\app.asar.unpacked\src\static\ssb-interop.js

code

// First make sure the wrapper app is loaded
document.addEventListener("DOMContentLoaded", function() {

   // Then get its webviews
   let webviews = document.querySelectorAll(".TeamView webview");

   // Fetch our CSS in parallel ahead of time
   const cssPath = 'https://raw.githubusercontent.com/mangohero1985/slack_css/master/custom.css';
   let cssPromise = fetch(cssPath).then(response => response.text());

   let customCustomCSS = `
   :root {
      /* Modify these to change your theme colors: */
	  --primary: #61AFEF;
	  --text: #ABB2BF;
	  --background: #282C34;
	  --background-elevated: #3B4048;
   }
   `

   // Insert a style tag into the wrapper view
   cssPromise.then(css => {
      let s = document.createElement('style');
      s.type = 'text/css';
      s.innerHTML = css + customCustomCSS;
      document.head.appendChild(s);
   });

   // Wait for each webview to load
   webviews.forEach(webview => {
      webview.addEventListener('ipc-message', message => {
         if (message.channel == 'didFinishLoading')
            // Finally add the CSS into the webview
            cssPromise.then(css => {
               let script = `
                     let s = document.createElement('style');
                     s.type = 'text/css';
                     s.id = 'slack-custom-css';
                     s.innerHTML = \`${css + customCustomCSS}\`;
                     document.head.appendChild(s);
                     `
               webview.executeJavaScript(script);
            })
      });
   });
});